The answer to What is a Lithium Battery becomes clearer when you separate the broad category from the rechargeable technology most people use every day. “Lithium battery” can describe primary lithium-metal cells that are designed for one-time use, as well as rechargeable lithium-ion cells used in phones, laptops, power tools, electric vehicles, solar storage, backup systems, and many other products. The rechargeable family is the main focus of this page because it is the technology most often compared, sized, charged, and integrated into modern power systems.
A rechargeable lithium-ion cell contains a positive electrode, a negative electrode, an electrolyte that carries ions, and a separator that helps keep the electrodes apart while still allowing ion movement. During discharge, lithium ions move through the electrolyte from the negative electrode toward the positive electrode while electrons travel through the external circuit. During charging, an external power source drives the process in the opposite direction. The U.S. Department of Energy provides a useful broader explanation of how batteries store and release energy.
Lithium batteries became important because they combine useful energy density, power, efficiency, low self-discharge, and long service life. The balance depends on chemistry and design. A phone battery, a LiFePO4 house battery, and an EV traction pack are all lithium batteries, yet they can differ sharply in voltage, construction, thermal behavior, power capability, charging limits, and cycle life.